This is a new Avengers Always - 5" line from Toy Business.

Top: Nova, Iron Man, Captain Marvel
Bottom: Hercules, Antman, Wonderman

Nova is a Nova helmet glued onto a robin head and a Capt. Summers from Starjammers body.

Iron Man is from the IM toy line 1994, with attachments from various other toys including Wolverine and Spider-man, repainted.

Capt. Marvel is an Iolaus body with a Peter Parker head.

Hercules is a Hercules figure and a Gorgon head.

Antman is a Godzilla fighter figure with a GI Joe helmet.

Wonder Man is a X-Men 2000 figure with a Jack head from Cadillacs and Dinosaurs.

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Top: Thor, Warbird
Bottom: Sersi, Captain America, Scarlet Witch, Wasp

Thor is from Cyborg Cable, repainted, and the head and mallet from Thor in the classic Avengers pack.

Warbird is a Zena repaint and so is Sersi.

Capt America is a Archangel II with a Capt. Am head and shield.

Scarlet Witch is a Topaz repaint.

Wasp is a repaint and wings made of plastic addition from a Voltron figure.